THE POLYMER SOCIETY OF KOREA

연구논문 초록집

초록 검색

세션명 Graduate Student Oral Session (I) (English)
발표장 제5회장
논문코드 O5-4
발표일 2024-04-3
발표시간 13:45-14:00
논문제목 Depolymerization of Poly(Ethylene Terephthalate) using Polyelectrolytes as an Efficient and Recoverable Catalyst
발표자 김용수
발표자 소속 서강대학교
저자 김용수, 김형준
소속 서강대학교
논문초록 Glycolysis has been considered one of the most promising pathways for converting poly(ethylene terephthalate)(PET) into monomeric feedstock—bis(2-hydroxyethyl) terephthalate (BHET)—which can be used as a starting material to produce virgin PET. In this process, metal-salts, such as zinc acetate, are generally used as a catalyst for glycolysis of PET. However, metal-based salt catalysts can be included in the final products, critically reducing the quality of the chemically recycled PET. Here, we present a new organic catalyst based on polyelectrolytes which offer excellent thermal stability, ease of separation and reusability. Among various types of polyelectrolytes, polyanion which synthesized based on imidazolium-acetate shows high depolymerization yields(>94%), while polycations show significantly lower efficiency.